Researchers at Rice University are spinning a bit of nano-based magic to create "coated sand" that has enhanced properties for water purification. The breakthrough may benefit developing countries where more than a billion people lack clean drinking water.
Beds of sand are commonly used throughout the world to filter drinking water. The particle size of sand and surface modifications determine the efficiency of sand in removing contaminants from water.
The Rice researchers’ technique makes use of graphite oxide, a product in the chemical exfoliation process of graphite (aka pencil lead) that leads to single-atom sheets known as graphene via subsequent reduction.
A team from the Rice lab of Professor Pulickel Ajayan published a report in the American Chemical Society journal Applied Materials and Interfaces describing a process to coat coarse grains of sand in graphite oxide; the resulting material is several times more efficient at removing contaminants than sand alone.
Nanosheets of graphite oxide can be tailored to have hydrophobic (water-hating) and hydrophilic (water-loving) properties. When mixed in a solution with sand, they self-assemble into coatings around the grains and keep the hydrophilic parts exposed. Adding aromatic thiol molecules to the coatings enhances their ability to sequester water-soluble contaminants.
Ajayan, a Rice professor in mechanical engineering and materials science and of chemistry, and his collaborators from Australia and Georgia conducted experiments to compare this coated sand with plain sand and activated carbon granules used by municipalities and in-home filtration systems.
The researchers ran two model contaminants -- mercury (at 400 parts per billion) and Rhodamine B dye (10 parts per million) -- through sand and coated sand placed into filtration columns. They found coarse sand's adsorption capacity of mercury was saturated within 10 minutes.
Beds of sand are commonly used throughout the world to filter drinking water. The particle size of sand and surface modifications determine the efficiency of sand in removing contaminants from water.
Rice University graduate student Wei Gao is researching ways to enhance plain sand with nanomaterials to improve its ability to remove contaminants from water.
Credit: Jeff Fitlow/Rice University
The Rice researchers’ technique makes use of graphite oxide, a product in the chemical exfoliation process of graphite (aka pencil lead) that leads to single-atom sheets known as graphene via subsequent reduction.
A team from the Rice lab of Professor Pulickel Ajayan published a report in the American Chemical Society journal Applied Materials and Interfaces describing a process to coat coarse grains of sand in graphite oxide; the resulting material is several times more efficient at removing contaminants than sand alone.
Nanosheets of graphite oxide can be tailored to have hydrophobic (water-hating) and hydrophilic (water-loving) properties. When mixed in a solution with sand, they self-assemble into coatings around the grains and keep the hydrophilic parts exposed. Adding aromatic thiol molecules to the coatings enhances their ability to sequester water-soluble contaminants.
Ajayan, a Rice professor in mechanical engineering and materials science and of chemistry, and his collaborators from Australia and Georgia conducted experiments to compare this coated sand with plain sand and activated carbon granules used by municipalities and in-home filtration systems.
The researchers ran two model contaminants -- mercury (at 400 parts per billion) and Rhodamine B dye (10 parts per million) -- through sand and coated sand placed into filtration columns. They found coarse sand's adsorption capacity of mercury was saturated within 10 minutes.
Beakers of solution containing mercury and Rhodamine B dye await purification through a new process developed at Rice University.
Credit: Jeff Fitlow/Rice University
The coated sand continued removing mercury for more than 50 minutes and resulted in filtered water with less than one part per billion. (The Environmental Protection Agency's maximum contaminant level goal for mercury in drinking water is two parts per billion.)
Results for water treated with Rhodamine B dye were similar.
The researchers found coated sand sequestered contaminants just as well as the commercially available active carbon filtration systems they tested.
The lab is looking at ways to further functionalize graphite oxide shells to enhance contaminant removal. "By attaching different functional moieties onto graphite oxide, we could engineer some form of a 'super sand' to target specific contaminants species, like arsenic, trichloroethylene and others," said Rice graduate student Wei Gao, primary author of the paper.
Co-authors are senior research scientist Lawrence Alemany, postdoctoral researcher Tharangattu Narayanan, and recent graduate Miguel Ibarra, all of Rice; Mainak Majumder, a former postdoctoral researcher at Rice, now a lecturer at Monash University, Clayton, Australia; and Bhabendra Pradhan, chief scientific officer at Nanoholdings LLC of Marietta, Ga.
Nanoholdings supported the research.
The coated sand continued removing mercury for more than 50 minutes and resulted in filtered water with less than one part per billion. (The Environmental Protection Agency's maximum contaminant level goal for mercury in drinking water is two parts per billion.)
Results for water treated with Rhodamine B dye were similar.
The researchers found coated sand sequestered contaminants just as well as the commercially available active carbon filtration systems they tested.
The lab is looking at ways to further functionalize graphite oxide shells to enhance contaminant removal. "By attaching different functional moieties onto graphite oxide, we could engineer some form of a 'super sand' to target specific contaminants species, like arsenic, trichloroethylene and others," said Rice graduate student Wei Gao, primary author of the paper.
Co-authors are senior research scientist Lawrence Alemany, postdoctoral researcher Tharangattu Narayanan, and recent graduate Miguel Ibarra, all of Rice; Mainak Majumder, a former postdoctoral researcher at Rice, now a lecturer at Monash University, Clayton, Australia; and Bhabendra Pradhan, chief scientific officer at Nanoholdings LLC of Marietta, Ga.
Nanoholdings supported the research.
Contacts and sources:
David Ruth
Rice University
Read the abstract at http://pubs.acs.org/doi/abs/10.1021/am200300u
A video demonstration of the process is available at http://www.youtube.com/watch?v=1nfddpRfEq0
Rice University
Read the abstract at http://pubs.acs.org/doi/abs/10.1021/am200300u
A video demonstration of the process is available at http://www.youtube.com/watch?v=1nfddpRfEq0
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